Saturday 25 November 2017

Le Chatelier's principle

Le Chatelier's principle

Le Chatelier's principle states that when any change is made to the conditions of an equilibrium the position of the equilibrium moves in the direction that minimises the change. Some reactions are reversible in dynamic equilibrium the rate of forward (right) reaction is the same as the backward (left) reaction concentrations of products and reactants stay the same and dynamic equilibrium can only happen in a closed system Can be any combination of reactants and products, doesn’t have to be half and half and effects of changes in conditions predicted by Le Chatelier’s principle.

  “If a system at equilibrium is disturbed, the equilibrium moves in the direction that tends to reduce that disturbance”

Rate of forward or backward reaction increases to minimise change both forward and reverse rates are speeded up equally and No effect on the yield . We get no more product, we just get it faster. Industrial equilibrium use compromise conditions that balance yield against reaction rate, cost and risks of equipment needed for conditions, side reactions and catalysts. Ammonia, ethanol and methanol are all produced industrially using a compromise temperature and pressure


The table below shows some of the properties that occur when Le chatelier's principle is in use: 



The equilibrium constant is the ratio of product concentration to reactant concentration which is raised to its appropriate power. this only varies for a reaction when the temperature is changed and it indicates whether the position of equilibrium to the left or to the right.


The equilibrium constant formula is: 




In industry a compromise may be needed between yield and rate  such as for exothermic reaction, a lower temperate gives you a higher yield and a lower temperature saves costs in terms of no need to pay for electricity to create heat or fuel on the other hand a lower temperature slows down the forward backward reactions so it would take longer to reach equilibrium.

**REMEMBER TO STAY POSITIVE LIKE A PROTON!!**

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